Kinetics and mechanism of reactions in solution – labile and inert complexes – ligand
displacement reactions in octahedral and square planar complexes – acid hydrolysis,
base hydrolysis and anationreactions. Trans effect – theory and applications – electron
transfer reactions – electron exchange reactions – complementary and noncomplementary types – inner sphere and outer sphere processes – application of electron
transfer reactions in inorganic complexes – isomerisation and racemisation reactions of
complexes. Molecular rearrangements of four- and six-coordinate complexes –
interconversion of stereoisomers – reactions of coordinated ligands – template effect and
its applications for the synthesis of macrocyclic ligands – unique properties.
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